ASTM F739-12e1

5.1 This test method is normally used to evaluate flat specimens from finished items of protective clothing and from materials that are candidates for items of protective clothing.

5.2 The breakthrough detection time, standardized breakthrough time, permeation rate, and cumulative permeation are key measures of the effectiveness of a clothing material as a barrier to the test chemical. Such information is used in the comparison of clothing materials during the process of selecting clothing for protection from hazardous chemicals. Long breakthrough detection times, long standardized breakthrough detection times, low amounts of cumulative permeation, and low permeation rates are characteristics of better barriers.

5.3 The sensitivity of the test method in detecting low permeation rates or amounts of the test chemical that permeate is determined by the combination of the analytical technique and collection system selected, and the ratio of material specimen area to collection medium volume or flow rate.

5.4 Comparison of results requires specific information on the test cell, procedures, and analytical techniques. Results obtained from closed-loop and open-loop testing may not be directly comparable.

5.5 A group of chemicals for use in permeation testing is given in Guide F1001.

5.6 These test procedures are also a part of ISO 6529. ISO 6529 provides a harmonized standard that also permits using some practices commonly followed in Europe for permeation testing, for example, using a breakthrough time normalized at a permeation rate of 1.0 µg/cm²/min instead of 0.1µg/cm²/min as used in this method. For this reason, the reporting of all permeation data must include the method that is used in the testing. Guide F1194 provides guidance on reporting permeation test results.

1.1 This test method measures the permeation of liquids and gases through protective clothing materials under the condition of continuous contact.

1.2 This test method is designed for use when the test chemical is a gas or a liquid, where the liquid is either volatile (that is, having a vapor pressure greater than 1 mm Hg at 25°C) or soluble in water or another liquid that does not interact with the clothing material.

1.3 Values states in SI units are to be regarded as standard. Values given in parentheses are not exact equivalents and are given for information only.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 7.