ASTM D6271-10(2016)

5.1 Environmental tobacco smoke consists of both vapor and particulate phase components. Due to the nature of vapor and particulate phases, they rarely correlate well, and an accurate assessment of ETS levels in indoor air requires determining good tracers of both phases. Among the attributes of an ideal ETS tracer, one critical characteristic is that the tracer should “remain in a fairly consistent ratio to the individual contaminant of interest or category of contaminants of interest (for example, suspended particulates) under a range of environmental conditions...” 5.2 To be able to quantify the contribution of ETS to RSP with a tobacco-specific marker is important because RSP is not specific to tobacco smoke. RSP is a necessary indicator of overall air quality; the Occupational Safety and Health Administration (OSHA) has previously set a PEL (permissible exposure level) for respirable dust in the workplace of 5000 μg/m³. However, RSP emanates from numerous sources 1.1 This test method covers the sampling/analysis of respirable suspended particles (RSP) and the estimation of the RSP fraction attributable to environmental tobacco smoke (ETS). The test method is based on collection of total RSP on a membrane filter, extraction of the filter in methanol, and determination of solanesol, a C₄₅ isoprenoid alcohol, by high performance liquid chromatography (HPLC) with ultraviolet (UV) detection.

1.2 This test method is compatible with the determinations of gravimetric RSP, ultraviolet particulate matter (UVPM), and fluorescent particulate matter (FPM) (see Test Methods D5955), but does not require them. UVPM and FPM, which are based on the ultraviolet absorbance and fluorescence of the filter extract, are also used to estimate the contribution of ETS to RSP.

1.3 The sampling components consist of a 1.0-μm pore size polytetrafluoroethylene (PTFE) membrane filter in a filter cassette connected on the inlet end to a particle size separating device and, on the outlet end, to a sampling pump. This test method is applicable to personal and area sampling.

1.4 This test method is limited in sample duration only by the capacity of the membrane filter. The test method has been evaluated up to 24-h sample duration; a minimum sample duration of 1 h is recommended.

1.5 Limits of detection (LOD) for this test method at a sampling rate of 2 L/min are 0.042 μg/m³ for 1-h sample duration and 0.005 μg/m³ for 8-h sample duration.

1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.7 This standard does not purport to address all the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.