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Standard Test Method for Hydroperoxide Number of Aviation Turbine Fuels, Gasoline and Diesel Fuels
Automaticky přeložený název:
Standardní zkušební metoda pro peroxid vodíku Počet letecké turbínové paliv, benzinů a motorové nafty
NORMA vydána dne 1.10.2013
Označení normy: ASTM D3703-13
Poznámka: NEPLATNÁ
Datum vydání normy: 1.10.2013
Kód zboží: NS-24555
Počet stran: 5
Přibližná hmotnost: 15 g (0.03 liber)
Země: Americká technická norma
Kategorie: Technické normy ASTM
Keywords:
aviation fuels, diesel fuel, gasoline, hydroperoxide, hydroperoxide number, turbine fuel, ICS Number Code 75.160.20 (Liquid fuels)
Significance and Use | ||||||||||
5.1 The magnitude of the hydroperoxide number is an indication of the quantity of oxidizing constituents present. Deterioration of the fuels results in the formation of hydroperoxides and other oxygen-carrying compounds. The hydroperoxide number measures those compounds that will oxidize potassium iodide. 5.2 The determination of the hydroperoxide number of aviation turbine fuels, gasoline and diesel is significant because of the adverse effect of hydroperoxide upon certain elastomers in the fuel systems. 5.3 The determination of hydroperoxide number of gasoline is significant because hydroperoxides have been demonstrated to decrease both Research and Motor Octane Numbers. In addition, hydroperoxides have adverse effects on certain fuel system components. 5.4 The determination of hydroperoxide number of diesel fuel is significant because hydroperoxides have been demonstrated to increase the Cetane Number. In addition, hydroperoxides have adverse effects on certain fuel system components. |
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1. Scope | ||||||||||
1.1 This test method covers the determination of the hydroperoxide content expressed as hydroperoxide number of aviation turbine, gasoline and diesel fuels. 1.2 The range of hydroperoxide number included in the precision statement is 0 to 50 mg/kg active oxygen as hydroperoxide. 1.3 The interlaboratory study to establish the precision of this test method consisted of spark-ignition engine fuels (regular, premium and California Cleaner-Burning gasoline), aviation gasoline, jet fuel, ultra low sulfur diesel, and biodiesel. However, biodiesel was not included in the precision calculation because of the large differences in results within labs and between labs. 1.4 This test method detects hydroperoxides such as t-butyl hydroperoxide and cumene hydroperoxide. It does not detect sterically-hindered hydroperoxides such as dicumyl and di-t-butyl hydroperoxides 1.5 Di-alkyl hydroperoxides added commercially to diesel fuels are not detected by this test method. 1.6 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. 1.7 This standard does not
purport to address all of the safety concerns, if any, associated
with its use. It is the responsibility of the user of this standard
to consult and establish appropriate safety and health practices
and determine the applicability of regulatory limitations prior to
use.
Standard Practice for Manual Sampling of
Petroleum and Petroleum Products Standard Specification for Reagent
Water Standard Test Method for Hydroperoxide
Number of Aviation Turbine Fuels by Voltammetric Analysis 4500-C1 B. Iodometric Method I--Standard Methods for
the Examination of Water and Wastewater Published by the American
Health Assoc., the American Water Works Assoc. and Water
Environment Federation. Available from American Public Health
Publication Sales, P. O. Box 753, Waldorf, MD 20604-0753. CRC Report No. 559 Determination of the Hydroperoxide
Potential of Jet Fuels Available from the Coordinating Research
Council, Inc., 219 Perimeter Center Parkway, Atlanta, GA 30346. |
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