ASTM G94-05 - 1.9.2005
 
Significance and Use

The purpose of this guide is to furnish qualified technical personnel with pertinent information for use in selecting metals for oxygen service in order to minimize the probability of ignition and the risk of explosion or fire. It is intended for use in selecting materials for applications in connection with the production, storage, transportation, distribution, or use of oxygen. It is not intended as a specification for approving materials for oxygen service.

 
1. Scope

1.1 This guide applies to metallic materials under consideration for oxygen or oxygen-enriched fluid service, direct or indirect, as defined in Section . It is concerned primarily with the properties of a metallic material associated with its relative susceptibility to ignition and propagation of combustion. It does not involve mechanical properties, potential toxicity, outgassing, reactions between various materials in the system, functional reliability, or performance characteristics such as aging, shredding, or sloughing of particles, except when these might contribute to an ignition.

1.2 This document applies only to metals; nonmetals are covered in Guide G 63.

Note 1

The American Society for Testing and Materials takes no position respecting the validity of any evaluation methods asserted in connection with any item mentioned in this guide. Users of this guide are expressly advised that determination of the validity of any such evaluation methods and data and the risk of use of such evaluation methods and data are entirely their own responsibility.

Note 2

In evaluating materials, any mixture with oxygen exceeding atmospheric concentration at pressures higher than atmospheric should be evaluated from the hazard point of view for possible significant increase in material combustibility.

1.3 The values stated in SI units are to be regarded as the standard.

This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

ASTM STPs in this category are listed as:

812, 910, 986, 1040, 1111, 1167, 1197, 1319, 1395, and 1454

G72-01

Standard Test Method for Autogenous Ignition Temperature of Liquids and Solids in a High-Pressure Oxygen-Enriched Environment

G88-21

Standard Guide for Designing Systems for Oxygen Service

G93-03e1

Standard Practice for Cleaning Methods and Cleanliness Levels for Material and Equipment Used in Oxygen-Enriched Environments

G124-18

Standard Test Method for Determining the Combustion Behavior of Metallic Materials in Oxygen-Enriched Atmospheres

G126-16(2023)

Standard Terminology Relating to the Compatibility and Sensitivity of Materials in Oxygen Enriched Atmospheres

D2512-17

Standard Test Method for Compatibility of Materials with Liquid Oxygen (Impact Sensitivity Threshold and Pass-Fail Techniques) (Withdrawn 2023)

D2863-23

Standard Test Method for Measuring the Minimum Oxygen Concentration to Support Candle-Like Combustion of Plastics (Oxygen Index)

D4809-18

Standard Test Method for Heat of Combustion of Liquid Hydrocarbon Fuels by Bomb Calorimeter (Precision Method)

G63-15(2023)

Standard Guide for Evaluating Nonmetallic Materials for Oxygen Service

G86-17

Standard Test Method for Determining Ignition Sensitivity of Materials to Mechanical Impact in Ambient Liquid Oxygen and Pressurized Liquid and Gaseous Oxygen Environments

G128-02

Standard Guide for Control of Hazards and Risks in Oxygen Enriched Systems